Authors:
Panait Veronica, Iarim Florentina
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
BactControl
Microbiological analyzer
Water treatment 
 
Abstract:
For water producers is important to monitoring the water quality. It is more important to know the surface water quality because from this type of water, drinking water is obtained (by clorination). Romanian legislations ask to monitoring the physicochemical and microbiological parameters. If the physico-chemical results are obtained up to maximum few hours, to obtain the microbiological results lasts couple of days. Because the drinking water process takes place continuously and in real time, physicochemical parameters are monitoring with on line sensors that allow us to ensure safe operation of the system. The study present the analysis made with on line analyzer at different types of water, to obtain microbiological results in the shortest time. The monitoring was performed in 2018, starting in June, finishing in November. The tests was made in collaboration with TehnoInstrument Romania and MicroLan- Netherlands.

Authors:
Scutariu Roxana-Elena, Puiu Diana, Nechifor Gheorghe, Iancu Vasile, Tatarus Alina, Galaon Toma
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Desorption
Microplastics
PET
Phthalates
Pollution 
 
Abstract:
Microplastic pollution has been an environmental issue that extends and worsen with the development of the plastic industry which increased exponentially since the early 1950s. DEHP, one of the microplastic related additives, is included in the list of priority hazardous substances, being an endocrine disrupter, reproductive system, affecting development and mobility for both humans and aquatic animals. According to literature data, DEHP is the most desorbed compound on microplastics, especially from polyethylene terephthalate. The aim of this study was to determine the level of phthalates (dimethyl phthalate – DMF, diethyl phthalate – DEF, dibutyl phthalate – DBF, di-2-ethylhexyl phthalate – DEHP, dioctyl phthalate – DOF) desorption from polyethylene terephthalate microplastics in surface water using in vitro laboratory tests. The samples were identified and quantified by gas chromatography coupled with mass spectrometry (GC-MS/MS).

Authors:
Iancu Vasile-Ion, Radu Gabriel-Lucian, Petre Jana, Galaon Toma, Scutariu Roxana,
Parvu Florilena, Paun Iuliana, Serban Gabriel
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Antidiabetics
Waste water
Contamination
 
Abstract:
To high grade antidiabetics consumption worldwide and to increasing number of prescriptions, these contaminants are founded in waste waters, rivers and ground waters. Effluents discharged from WWTP contaminates the rivers and thus, it is necessary to investigate the occurence of antidiabetic compounds in waste waters. The aim of this work was to detect 3 antidiabetic (glyburide, glimepiride and repaglinide) contaminants in waste water treatment plant using SPE-LC/MS/MS method. 

Authors:
Puiu Diana, Scutariu Roxana, Iancu Vasile, Tatarus Alina, Niculescu Marcela, Galaon Toma
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Acidic herbicides
Pyridiyncarboxylic acid
Derivatization
GC-MS/MS
Solid phase extraction 
 
Abstract:
GC-MS/MS method are often used in analytical determination of pesticides due to its high sensitivity, compounds selectivity and good separation. Auxin pyridine herbicides as clopyralid, dicamba, triclopyr and fluroxypyr are polar compounds which require structural modifications in order to be volatilized and then separated on most used capillary columns. Because there are limited applications of in-port derivatizations and GC-MS/MS detections of these herbicides, a new method for these compounds was developed. Silylation reactions, especially with MTBSTFA, are mainly chose as an alternative to alkylation in order to avoid secondary interference products.  The above mentioned compounds are usually found in environmental samples, like surface water, soil and biota.   

Authors:
Puiu Diana Maria, Scutariu Roxana, Vasile Iancu, Tatarus Alina, Pascu Luoana Florentina, Galaon Toma
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Acidic herbicides
Chlorophenoxycarboxylic acid
Derivatization
GCMS/MS
Solid-phase extraction 
 
Abstract:
A sensitive GC-MS/MS method was developed for the determination of five important chlorophenoxycarboxylic herbicides from surface water: 2,4 D (2,4dichlorophenoxyacetic acid), MCPA (4-chloro-2-methylphenoxyacetic acid), 2,4 DB (2,4-dichlorophenoxybutyric acid), MCPB (4-chloro-2-methylphenoxybutyric acid), 4 CPA (4-clorophenoxyacetic acid). The analytical challenge in the determination of the acidic herbicides by GC consists in an additional derivatization step due to the –COOH polar group. GC-MS/MS is used to increase the sensitivity for the quantification of TBDMS (t-buthyldimethylsilyl) derivatives which are often used in MS separations because of the easily fragmentation of molecular ion.

Authors:
Mitru Daniel, Lucaciu Irina Eugenia, Gheorghe Stefania, Stoica Catalina,
Banciu Alina Roxana, Ionescu Lucian, Ionica Daniela Liliana, Nechifor Gheorghe
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Activated sludge
Linear alkybenzene sulfonates(LAS)
Nonylphenol ethoxylates (NPE)
Surfactants
 
Abstract:
The surfactants are one of the most commonly used class of chemicals (15billions tons per year) in various applications: household cleaning, personal care products and industry. Anionic surfactants represent the major class of surfactants used in detergents, the predominant groups being linear alkylbenzene sulphonates (LAS) and linear alkyl suphates (AS). Non-ionic surfactants are used in large quantities in domestic and commercial products, e.g. cleaning solutions. The most widely used non-ionic surfactants are alkylphenol ethoxylates (APEs) and the most used commercial APEs are octylphenol ethoxylates (OPEs) and nonylphenol ethoxylates (NPEs). Because of the large utilization of surfactants, they can accumulate in the domestic and industrial wastewaters, affecting treatment plants (WWTP) due the inhibition off activated sludge. As a result, surfactants could affect the water bodies quality through discharge of WWTPs’ effluents or soil quality through various modes of sludge disposal. 

Authors:
Chiriac Florentina Laura, Paun Iuliana, Pirvu Florinela, Iancu Vasile,
Tatarus Alina, Lehr Carol Blaziu, Pascu Luoana Florentina, Galaon Toma
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Endocrine disruptors
LC-MS/MS
Metabolite
Wastewater 
 
Abstract:
Contamination of wastewater from wastewater treatment plants (WWTP) and their discharge into the emissaries is one of the main environmental problems nowadays, due to micro pollutants that are present in concentrations in the order of ng/L or μg/L. A significant part of these contaminants end up in the environment either not transformed or as metabolites contributing to environmental pollution, with a negative impact on human health and wildlife. Among this type of micro pollutants, Bisphenol A (BPA) is an endocrine disruptor with high estrogenic activity and with increased presence in the environment. Similar to other emerging contaminants, Bisphenol A, well known for its endocrine disruptor properties, may undergo different transformations depending on the environment or the technological treatment processes sometimes producing transformation products or metabolites that can have a different ecotoxicological behaviour and profile. The most common metabolite of BPA is 4-hydroxy-acetophenone. In this study a new LC-MS/MS method was developed and optimized for detection of BPA and BPA metabolite, 4hydroxyacephenone in wastewater samples which, after treatment, are discharged in emissaries.

Authors:
Catrina (Traistaru)Gina Alina, Kim Lidia, Pascu Luoana Florentina, Serbanescu Agnes,
Cernica Georgiana, Cristea Ionut, Barbu Mona
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Ash
Biomass waste
ICP-MS
Valorisation 
 
Abstract:
The recycling and reuse of the biomass wastes as added-value materials, for different productive sectors is essential from an economic and environmental perspective. The advantage of this process consists in reducing costs for biomass power producers and favoring the development of a circular and sustainable economy. The biomass wastes transformed in pellets and briquettes are used as secondary biofuels in combustion plant. The characteristics of biofuels, which will influence the combustion plant, are the moisture, ash content, net calorific value, the proportion of volatile matter, combustible carbon content and also the toxic metals content. The excessive accumulation of toxic metals such as As, Cd, Pb in some biomass waste presents a risk for human health. 

Authors:
Diodiu Raluca, Iancu Vasile, Bratu Mihai, Petrescu Mihaela, Danciulescu Valeriu
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Acetic acid
Aldehyde
Formaldehyde
Formic acid
Indoor air
 
Abstract:
A person is subjected to chemicals from air at home and in the environment in which they work. Thus, indoor air intake can be considered an important factor in human exposure to hazardous pollutants. In addition, children have a higher susceptibility to environmental pollutants than adults because they breathe larger volumes of air in relation to their body weights and their tissues and organs are still growing. Aldehydes, including formaldehyde, are among the most dangerous pollutants found in schools and kindergartens. 

Authors:
Stoica Catalina, Dinu Laurentiu, Lucaciu Irina, Nita-Lazar Mihai, Oncu Voicu
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Benthic invertebrates
Hondol River
Mine water 
 
Abstract:
The use of biological models for freshwater quality assessment was one of the main objective of Water Framework Directive (2000/60/EC), due to their ability for longterm retaining both structurally and functionally, the direct and indirect effects of pressure factors. One of the most appropriate biological models are the benthic invertebrates. They are very heterogeneous taxonomic group that presents a broad spectrum of responses to each form of stress, including chemical pollution and morphological changes of aquatic habitat.  

Authors:
Barbu Luminita
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Disinfection by-products
THMs formation
Water chlorination 
 
Abstract:
In the water treatment process, in order to ensure the microbiological safety of the drinking water, chlorine is a commonly used disinfectant. During disinfection, chlorine may react with natural organic matter in the raw water, resulting in various disinfection by-products (DBP) formation, such as trihalomethanes and haloacetic acids, with potential human health risks. DBP formation varies with quality of water source: concentrations and properties of natural organic matter, chlorine dose, contact time water – chlorine, temperature, pH. 

Authors:
Marty Jean Louis
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Array sensor
Biosensor
BOD5
Neurotoxicity 
 
Abstract:
Toxic substances menacing to the humans, agriculture, livestock and wildlife may contaminate the aquatic resources and portable water system such as heavy metals, toxins, and environmental pollutants. In the last decades, the liberation of industrial effluents containing new xenobiotic compounds such as pharmaceuticals, endocrine disruptors, surfactants, and industrial additives to water resources has became a serious concern. The worldwide different regulatory authorities has set the regulatory standards for these contaminants but the permissible limits are in very low concentration i.e. pg/L or ng/kg. In consideration of toxicity and ubiquity of these compounds, the development of fast, sensitive and reliable detection methods are of immense need. Some conventional analytical methods are commonly used for the control of the environment. These methods possess low detection ranges, the disadvantages such as lack of on site performance, high cost and requirement of highly trained professionals limit their applications and are therefore difficult to establish specially in the developing countries. To overcome the above limitation, the traditional and novel screening methods have found a wide application in screening of water quality.

Authors:
Tevi Giuliano, Stoica Alexandra
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Contaminated sites
Groundwater models
Spatial data
Remote sensing
GIS
 
Abstract:
The rising trend of urbanization in Romania is resulting in higher population densities in the peri-urban areas. However, the fast-paced urbanization process is surpassing the ability of the developing cities to provide adequate infrastructure and facilities to its inhabitants, creating major environmental issues. In many cases, the proposed solutions to these problems are not an integrated part of an environmentally sustainable planning, but rather uncorrelated solutions (independent sanitation solutions, groundwater catchment areas etc). 

Authors:
Cristea Nicolae Ionut, Constantin Lucian Alexandru, Nitoi Ines,
Constantin Mirela Alina, Stefanescu Mihai, Nechifor Gheorghe
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Bisphenol A
Derivatization
Trifluoroacetic anhydride
Waste water 
 
Abstract:
Bisphenol A, (BPA), is largely used in the production of epoxy resins and polycarbonate plastics as additive and antioxidant. Approximately one million tons of BPA where used only in EU annually. From municipal wastewater and industrial discharge, large quantity of BPA of introduced into the aquatic environment. For determination of bisphenol A in environmental water most frequently used methods are based on liquid chromatography and gas chromatography. As BPA is a phenolic compound, its volatility is relatively low, resulting in poor sensitivity and peak tailing using gas chromatography. To improve analytical performances derivatization is necessary. Stehmann and Schröder previosy studied derivatization of BPA with trifluoroacetic anhydride (TFAA) and characterized formed derivative by massspectra, infrared-spectra and the results of the NMR spectroscopy, but no analytical method for BPA using derivatization with TFAA was developed.

Authors:
Catalina Mihaela Helepciuc (Gradinaru), Marinela Barbuta, Adrian Alexandru Serbanoiu,
Andrei Burlacu
Conference: International Symposium “The Environment and the Industry”
Date: September 20-21, 2018
Location: Bucharest, Romania
Published: 2018
Keywords:
Corn cob
Density
Fly ash
Mechanical properties
 
Abstract:
The research presented in this paper aim to analyze the effects of cement replacement by fly ash in 10 vol. %, 20 vol. %, and 30 vol. % and, afterwards, the effects of mineral aggregates substitution by 50 vol. % with vegetal aggregates. The used vegetal aggregates were shredded corn cobs, and were investigated the density, the compressive and split tensile strength of concrete. The results revealed that fly ash, as cement partial replacement, decreased the compressive strength comparing to the reference concrete, meanwhile, the splitting tensile strength was improved when were used 10% and 20% vol. of fly ash. Fly ash had a positive effect on the compressive strength of the vegetal concrete, in the case of the composition with 10% and 30% vol. of industrial waste, and also on splitting tensile strength in the case of 10% and 20% vol. of replacement rate. The concrete density diminished with 1.67%, 3.12% and 3.82% in the case of 10%, 20% and 30% vol. cement replacement by fly ash, respectively. Corn cob aggregates led to a concrete density decreasing with almost 25% compared to reference concrete.

Authors:
Mihai Ciobanu, Tudor Lupascu, Tatiana Mitina, Igor Povar
Conference: International Symposium “The Environment and the Industry”
Date: September 20-21, 2018
Location: Bucharest, Romania
Published: 2018
Keywords:
Activated carbon
Adsorption 
Aqueous solution
Chemical activation
Dynamic conditions
Nut shells
 
Abstract:
In the paper the eliminating strontium ions from groundwater by using the CAN-7
activated carbon under dynamic conditions has been studied. The activated carbon
CAN-7 is obtained by the chemical method, through the treatment with orthophosphoric acid at distinct temperatures. It has been proved that by the reduction of
the filtration rate of the solution containing strontium ions through the adsorbent
column, the strontium ion adsorption is increased. The adsorption of strontium ions
from aqueous solutions on the CAN-7 activated carbon has been measured at
different lengths of working layer of the adsorbent column and at different filtration
rates of the solution. The length of working layer of the column with CAN-7 has
been determined as a function of the initial concentration of strontium ions and
filtration rates. The activated carbon CAN-7 with adsorbed strontium ions is
completely regenerated by 0.36% of hydrochloric acid. The obtained results for the
process of adsorption of strontium ions from aqueous solutions on the CAN-7
activated carbon under dynamic conditions has demonstrated the option of removing
this pollutant from the deep waters.

Authors:
Ilie-Cosmin Cantar, Ion Chisalita, Lucian Dinca
Conference: International Symposium “The Environment and the Industry”
Date: September 20-21, 2018
Location: Bucharest, Romania
Published: 2018
Keywords:
Black locust
Cooper ore
Oleaster
Tailing dumps
Wood
 
Abstract:
The present paper emphasizes the possibility of using wood from the plantations installed on waste heaps by analysing the density of wood mass and establishing the biomass of species planted on the waste heaps from Moldova Noua. In order to determine wood biomass for the analysed species, wood samples were gathered from a specific sample area. As such, their volume and mass were established both
before and after drying them in a stove at a temperature of 105 degrees Celsius for 24 hours. The plantations biomass was calculated by using wood density according to the work method previously described as well as the wood mass volume per hectare. The last element was determined after biometric measurements realized in
12 sample surfaces of 100 square meters each, arranged in four variants with three recursions. In the specific case of Moldova Noua waste heaps, the values obtained for wood density attest the high-quality wood of these plantations from the point of view of their density, in comparison with the wood from similar species grown
under favourable vegetation conditions. Furthermore, analysing the productivity of plantations installed on the waste heaps from Moldova Noua, attest the framing of these plantations in an inferior production class from a productive point of view. The papers conclusions discuss the obtained results in the context of data from specialty literature concerning the productivity and wood density of forest plantations from the waste heaps located in Moldova Noua.

Authors:
Irina Senicovscaia, Tatiana Grozova, Georgiy Poleshchuk
Conference: International Symposium “The Environment and the Industry”
Date: September 20-21, 2018
Location: Bucharest, Romania
Published: 2018
Keywords:
Anolyte water
Squalene
Fodder protein
Growths activation
S. fibuligera Y-436
 
Abstract:
The phenomenon of growth activation of the industrial strain of mycelial fungus S.
fibuligera Y-436 under the influence of squalene and anolyte water has been
investigated. Squalene had a stimulating effect on the growth of the strain on YEPD
Broth in all doses. The stimulating effect of squalene was maintained for 54 hours,
in a dose of 0.0005% – up to 78 hours of the strain cultivation under aerobic
conditions. The growth rate of the strain in the exponential phase between 4 and 6
hours on medium with a squalene of 0.0005 % is 0.30, 0.001 % – 0.44, 0.002 % –
0.41, on medium without squalene – 0.24. Squalene promotes faster adaptation of
the strain to the substrate and reduces the duration of its lag phase of growth by 2-4 hours. The number of cells increases by 2.2-2.3 times with the use of squalene in
doses of 0.0005-0.001 % after 24 hours and by 1.4 times after 48 hours of
incubation on the nutritional mixture based on wheat flour. The strain reached the
stationary phase after 24 hours of cultivation with the use of squalene, while in the
control variant – after 48 hours. This reduces the duration of cultivation by 2 times.
Anolyte water contributed to the rise of generative activity of the strain due to the
acid reaction by 34.3 % in comparison with the initial water. The most effective
method of activation of the strain is the combined use of anolyte water and squalene in a dose of 0.0005-0.001 %.

Authors:
Konstantza Tonova, Madlena Lazarova
Conference: International Symposium “The Environment and the Industry”
Date: September 20-21, 2018
Location: Bucharest, Romania
Published: 2018
Keywords:
Alga
Carbohydrate
Hydrothermal hydrolysis
Ionic liquid
Ulva sp.
 
Abstract:
Macroalgae represent a worldwide spread renewable source of valuable
biopolymers, polysaccharides and proteins that after pretreatment constitute an
intermediate platform for microbial and chemical production. In the present study
the potential of some ionic liquids (ILs) to extract and hydrolyze the algal
carbohydrates derived from Ulva sp. is examined and compared to the conventional
inorganic acid catalysts, H2SO4 and HCl. The experimental results reveal that the IL,
1 -butyl-3-methylimidazolium acetate, is superior to both acid auxiliaries in
extracting carbohydrates. The capacity of this IL for splitting reducing sugars under
the conditions of hydrothermal hydrolysis is comparable with the power of HCl, but
higher than HCl in terms of monosugar fraction and protein released. The highest
yields of reducing and monosugars and of protein are obtained by using the strong
dibasic acid, H2SO4. It could, however, produce dehydration by–products which
would incur inhibition of enzymatic and microbial processes fed by the algal liquor.
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