Authors:
Cernica Georgiana, Arama Georgeta Madalina, Cuciureanu Adriana, Catrina (Traistaru)Gina, Stroia Diana 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Dissolved organic carbon
Hazardous
ndustrial waste
Inert
Nonhazardous

Abstract:

The paper presents the influence of pH on the dissolved organic carbon in industrial waste samples as a decision indicator in determining the hazardousness of the waste at storage according to the environmental legislation. Waste storage is a common method of management and is realizing according to GO 95/2005, which requires limit concentrations of the indicators analyzed according to each type of deposit (inert, non-hazardous, and hazardous). For the analysis of the dissolved organic carbon, 6 samples of waste from different sectors of activity were subjected to the leaching test and the eluate was analyzed on a multi N/C 3100 equipment at both the pH of the waste, itself and between 7.5 and 8 pH units. From the results obtained it is found that the modification of the pH leads to significant variations in the concentration of the dissolved organic carbon, variations which can provide essential information for the subsequent management of the waste.

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Authors:
Komitov Georgi, Rasheva Violeta, Binev Ivan 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Biomass
Green energy
Energy efficiency
pellet quality 

Abstract:

A methodology for quickly and easy determination the quality of pellets offered on the market is developed on the basis of “theory of graphs”. The pellet quality assessment is performed in two ways – by direct control (non-destructive measurements) and by combustion. The following pellets parameters are determined at the direct control stage: friability, homogeneity, presence of dark stains and moisture content. The experimental measurement of following parameters of the combustion process is carried out at the stage of pellet burning assessment under real conditions: temperature in the combustion chamber, time for complete combustion of the pellets and the amount of ash after pellets combustion. The calorific value of the tested pellets is determined on the basis of the experimentally obtained parameters of the combustion process. The the obtained parameters values are statistically processed according to the described in the paper equations at the next stage. Then the results for the investigated pellet parameters are compared with the normative values. The proposed methodology could be calibrated by experimental determining the calorific value of investigated pellets by a calorimeter. Practical application of this methodology is that by not so complicated measurements and calculations the required amount of pellets for heating a building with a certain energy consumption for heating season could be determined.

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Authors:
Ivanova Nevena, Filipova Margarita, Zheleva Ivanka 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
End of waste
Recovery process
Recycling
Tyre 

Abstract:

The main objective of the study, presented in the article, is to review the possible methods of final recovery of End-of-Life Tires (EOLT). Applied methods of the end-use of EOLT used in Republic of Bulgaria and in some other countries in the European Union are presented and commented in the paper. Also the end-use of EOLT waste criteria is discussed. The possibilities for post-recovery including recycling of the waste generated by the tire recovery process have been explored. The application of the identified methods in Republic of Bulgaria and other European Union Member States have been analyzed and assessed.

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Authors:
Chera Anghel Irina Alina, Popescu Loredana 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Biodegradability
Characteristics
Mineral oil
Liquid ester
Investigations

Abstract:

The most commonly used insulating liquid in transformers is mineral oil. Special synthetic applications such as silicone, ester, perchloroethene, etc. are used today in special applications, with different characteristics, very low or nonexistent toxicity to mineral oils used in transformers. On the other hand, they have a much better biodegradability than mineral oils in both aerobic and anaerobic conditions. But they cannot directly replace the mineral oil in operation or in repaired units. They have dielectric properties and good heat transfer but have limited their use to special transformers due to the relatively high cost and availability.

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Authors:
Vizitiu Diana Elena, Dinca Lucian, Enache Viorica, Donici Alina, Radomir Ana-Maria 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Drought
Forest shelter-belts
Genotype
Grapevine
Temperature 

Abstract:

Climatic conditions from areas where vine is cultivated or intended to be cultivated are essential and important to be acknowledged especially in the context of climatic changes that have taken place during the last 50 years. In this regard, prevention solutions are recommended to be implemented as well as solutions that decrease the damages caused by climatic changes or other stress factors. Among these solutions we mention the reorientation of vine areas, planting shelter-belts in areas and regions exposed to high intensity winds, reconsidering the structure of viticultural varieties or selecting the cultivated vine varieties.

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Authors:
Lybenova Mariyana, Chikalanov Alexandre, Petkov Yulian 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
PES scheme
Structural model
Forest
Water quality
Web platform 

Abstract:

The publication deals with the development of a structural model of payment schemes for ecosystem services (PES) oriented to usage of forests for water, soil and microclimate quality improvement. Proposed structural model is built on the Meta analyses base of more than 50 PES schemes worldwide. The proposed structural model has three top down levels – groups of categories, categories and attributes. There are seven groups of categories, 17 categories and more than 120 attributes. The structured information about studied PES schemes is stored in a warehouse managed by unique web platform created by the authors. An important part presented study is the developed generic use case of PES schemes with definition of seven participated actors.

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Authors:
Hvarchilkova Denitsa, Filipova Margarita, Zheleva Ivanka 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Construction waste
Recovery process
Recycling
Re-using

Abstract:

For environment protection in the European Union (EU) it is very important the construction waste to be recycled and reused. The potential for the construction waste recycling and reuse is high, as their components have high cost. There is an opportunity for re-use of such materials in road construction, for drainage systems, for outdoor sports grounds and other construction sites. In 2012 a regulation on the management of construction waste and on the use of recycled building materials was adopted in Bulgaria, aiming to introduce a new model for the management of construction waste. This would guarantee: creation of favorable legislative and economic conditions for implementation of technologies ensuring the achievement of recycling and recovery targets but which are also financially viable in line with the country’s incomes; identifying the persons responsible for covering the costs of building waste management and achieving the recycling and recovery targets; creating conditions for the production and marketing of materials from recycling of construction waste at a price that is competitive with the same new raw materials used in construction. The main effect expected from this normative document is to contribute to Bulgaria’s development towards European trends, 

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Authors:
Danciulescu Valeriu, Pascu Luoana Florentina, Petrescu Mihaela, Cozea Andreea,
Diodiu Raluca, Tanase Gheorghita, Pasca Maria 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Air
Concentrations
Emissions
Particles
Pollution 

Abstract:

Particulates generated by anthropogenic activities are found in the ambient air in varying amounts, in a wide range of sizes and in a wide variety of chemical composition. The concentration of particulates at one site, as well as their composition, are influenced by their origin and dispersion factors. By chemical and dimensional analysis of particulates in an area, we can draw preliminary conclusions about the origin and level of pollution in that area. This paper presents the results obtained by concomitant monitoring of particulates emissions and the concentration of particulate matter in ambient air in the adjacent area of an industrial plant. The result of the measurements obtained and their correlation with the specific conditions during the monitoring period lead us to the conclusion that the concentration of particulate matter at the emission sources directly influences the concentrations of particulate matter in the neighbouring area.

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Authors:
Olariu Andra, Palcu Marin
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Ammonium origin
Ammonium plume
Groundwater flow
Mass transportation modeling
Mineral waters 

Abstract:

In many cases in Romania, the mineral waters (in the Neogene Volcanic area of the Eastern Carpathians), especially the carbonate waters, have ammonium in concentration over 0.5 mg/l. The main issue regarding the presence of ammonium is identifying if the concentration is due to the anthropogenic pollution or it is of endogenic origin. The geological, hydrogeological and hydrochemical data analysis resulted in a conceptual model of the aquifer’s spatial position, groundwater movement and mineralization, and ammonium occurrence. The geological and tectonic aspects, aquifer’s recharging, groundwater flow direction, absence of surface pollution sources and correlation of hydrochemical data, all indicate the underground origin of ammonium. The aquifer is generated in pliocene – quaternary granular deposits. In the basement of these granular deposits, in the fracture areas, the groundwater is mixed with carbon dioxide and ammonium emissions, produced in the volcanic chambers. The surface data correlation and the hydrochemical data analysis resulted in the confirmation of the deep ammonium origin. After groundwater flow modeling and ammonium transport simulation, the ammonium plume size and preferential transport directions have been finally elucidated.

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Authors:
Isvoranu Gheorghita, Popescu Daniela Ionela, Codrici Elena, Mihai Simona, Enciu Ana-Maria, Manda Gina, Peretto Marco, Tanase Cristiana 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Non-acute lead toxicity
Haematology
Anxiety
Rat 

Abstract:

Lead, a high-risk environmental pollutant and extensively used by industry, is one of the most widely outspread toxic metal today. Lead toxicity is a public health problem both for the children and for the adults. Lead does not have any useful functions in the body, instead it produces only harmful effects once it gets into the body. In this study, we investigated the toxicity of lead in an animal model of non-acute exposure. Experimental groups received treatment of aqueous solution lead acetate at different doses and time of administration. Toxic effects of lead were investigated on haematological and behaviour of treated rats. We noticed the disturbances of both haematological parameters and behaviour. Our results indicated that non-acute exposure to lead induced toxic effects in the blood, and central nervous system of adult Wistar rats.

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Authors:
Kovacs Marius, Calamar Angelica-Nicoleta, Toth Lorand, Simion Sorin, Simion Alexandru 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
 BAT
Metallic
Pollution
Surfaces
Water 

Abstract:

The main activity of the studied company is treatment and coating of metals (galvanizing plating), trapping and treatment of waste water. Galvanizing consists in creating a superficial diffusion layer of iron alloy. BATs (Best Available Techniques) do not necessarily mean the most advanced technique available, but the best technique from an economic point of view for a particular installation. Results of the research relate to compliance of the industrial water treatment plant to BAT best available techniques, in order to minimize pollutants discharged into the sewerage network. Furthermore, the current paper identifies possible dysfunctional problems of the galvanizing plant and of the sewage treatment plant and makes suggestions of remedies for possible technical and organizational problems.

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Authors:
Rodino Steliana, Butu Marian, Ion Raluca 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Bioeconomy
Circular economy
Romania
Waste management   

Abstract:

The waste management strategies released and applied in EU countries endeavor to achieve the improvement of natural resources use and efficiency towards reducing the air, water and soil pollution due to improper waste disposal or treatment. This paper is a blueprint on waste generation and waste management Policies, Laws and strategies existing in Romania compared to EU countries. According to Directive 2008/98/EC Waste, is defined as “any substance or object which the holder discards or intends or is required to discard”. One of the main principles of waste management strategies is to be able to process the waste generated towards reaching as up as possible the Waste Management Hierarchy. From the circular economy concept point of view, the incorrect treatment of waste is representing an important loss of resources, both in raw materials and energy and therefore recycling and reuse should reach a superior level every year.

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Authors:
Pirvu Florinela, Cruceru Liliana, Niculescu Marcela, Petre Jana, Iancu Vasile-Ion, Pascu Luoana Florentina, Galaon Toma 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Pollution index
Water quality index
Wastewater 

Abstract:

Global population growth is associated with an increase in the amount of water used. A consequence of this increase is the high amount of wastewater volume resulted, which can affect ecosystems balance. For this reason, the authorities are forced to account and improve wastewater treatment processes to minimize environmental impact. The physical-chemical properties of the effluent are unique and depend on the origin of the leakage, the sewer system infrastructure, the level of development of the area, the climatic conditions, and hence the wastewater stream has a unique composition of organic and inorganic loads. For a quick and easy understanding of wastewater quality, two types of water quality indices were developed. This study presents the results of a complex analytical investigation of effluents discharged from six rural WWTP’s situated in southern part of Romania compared with a simplified interpretation of wastewater quality by using a pollution index (PI) and a wastewater quality index (WWQI). Data recorded with a monthly frequency between 2013 and 2017 were used. Regarding the WWQI values calculated in this study, all wastewater analysed from the six WWTP’s, fit to the ‘Marginal’ Designation.

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Authors:
Tatarus Alina, Puiu Diana, Scutariu Roxana, Simion Marius, Niculescu Marcela Antoaneta, Galaon Toma 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
PCB congeners
Municipal waste water treatment plants
Sewage sludge
Romania

Abstract:

Sewage sludges originating from waste water treatment plants (WWTP) act as a sink for various contaminants including polychlorinated biphenyls (PCBs). The fate of organochlorine compounds in sewage sludge is shaped by their physical-chemical properties and by environmental conditions. The high persistence of polychlorobiphenyls (PCBs) in sewage sludge is given by an extremely reduced degradation rate which varies from months to years (the half-life of PCB 28 is 10.9 years, and PCB 52, 11.2 years). Due to their increased hydrophobicity, these carcinogenic compounds can be easily uptake by plants and transferred to the food chain. The present study investigated the occurrence of these seven PCB congeners in sewage sludge sampled from municipal waste water treatment plants from different geographical areas in Romania for a two-year period (2018 and 2019). For the analyzed PCB congeners a database was created concerning their occurrence levels in sewage sludge from these WWTPs. A total number of 62 sewage sludge samples were collected from different WWTPs between 2018-2019 and analyzed for PCB congener content using a validated GC-ECD method .

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Authors:
Marin Nicoleta Mirela, Batrinescu Gheorghe, Nita-Lazar Mihai, Pascu Luoana Florentina, Lehr Carol Blaziu 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
First derivative spectrometry
Multicomponent analysis
Procaine hydrochloride
Procainamide hydrochloride
Lidocaine

Abstract:

Two spectrometric methods have been developed for quantitative simultaneous determination of procaine hydrochloride (PH·HCl), procainamide hydrochloride (PHA·HCl) and lidocaine (Lid) from synthetic mixture. The methods employed are first derivative spectrometry, using zero crossing method and multicomponent analysis which is based on the additivity law. Using first derivative spectrometry, the wavelength selected for the quantitative determination of PH·HCl was 237 nm for Lid was 242 nm and for PHA·HCl was 290 nm in mixture. The method is linear when the concentration ranged between 6.62-9.93 μg/mL for PH·HCl, 6.43-9.64 for PHA·HCl and 5.56-8.35 for Lid. The multicomponent analysis is a direct method and involves the absorbance measurements of at three different wavelengths. The molar absorption coefficients values were calculated at each wavelength and the concentration of PH·HCl, PHA·HCl and Lid from mixture was determined by solving matrix using Cramer’s rule. The recovery of each compound in mixture was calculated and it is 101.4 % for PH·HCl, 100.4 % for PHA·HCl and 98.4 % for Lid.

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Authors:
Rada Elena Cristiana
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Economic sustainability
Emissions
Impact
Industrial
Odour
Particulate matter 

Abstract:

In the industrial sectors, the ways of release pollutants into the atmosphere can vary significantly. We can find various combinations of primary conveyed emissions, secondary conveyed releases, diffused emissions, depending on the characteristics of the industrial plant. When an environmental impact assessment is performed, discussion concerns mainly the impact on the public health, whilst the occupational impact of these releases is moved to other contexts. The present paper zooms on selected case studies in order to understand the consequences of different way of pollutant release on the outdoor and indoor air quality at the site of the plant (within the fence). Two kinds of pollutants were selected: particulate matter and odoriferous substances. Results demonstrate that the industrial sector is unbalanced: the regulations in force in EU give different attention to the impact of the releases to the atmosphere depending on the industrial sector. In particular, in some sectors the impact of diffused emissions is underestimated because of a raw management of their control. Some preliminary proposals are put forwards for a better management of the emissions to the atmosphere in potentially critical cases. These proposals are based on the concept that conveyed solutions for pollutant release must be preferred, with the care of designing the related stacks with an optimised combination of stack height, conveyed gas velocity, 

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Authors:
Koval Iryna Z.
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Bubbling
Cavitation
Destruction degree
Gas
Microorganisms

Abstract:

Comparison of values of destruction degree of microorganisms of different types (Micrococcus luteus, Pseudomonas fluorescens, Bacillus cereus, Sarcina lutea bacterias and Saccharomyces yeasts) under the simultaneous treatment of water by cavitation and gas is carried out. Has been determined the nature of the gas in which the cells were most actively destroyed by comparing the values of destruction degree. The greatest effectiveness of microorganisms destruction was achieved with the Ar/US-action, regardless of the type of microorganisms, their morphological characteristics and their initial amount per unit volume of water. Morphological features have an influence only on the duration of cavitation treatment of water.

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Authors:
Scaeteanu Gina Vasile, Madjar Roxana Maria, Peticila George Adrian 
Conference: International Symposium “The Environment and the Industry”
Date: 26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Health
Nitrate
Nitrite
Pollution
Well water 

Abstract:

Drinking water quality is an actual and stringent problem and the presence of nitrate and nitrite ions above limits imposed by legislation may produce methemoglobinemy and different types of cancer. Because nitrate is odourless, colourless and tasteless is undetectable without tests and well water is recommended to be evaluated from this point of view, especially when in the proximity of the wells are activities which may contribute to water contamination. The present research was carried out with aim to achieve nitrate and nitrite levels from wells located in three areas from Muntenia region: Chiajna (Ilfov), Letca Noua (Giurgiu) and Manastirea (Calarasi). The obtained results evidenced that 10 from 14 analysed wells contain nitrate levels were over imposed limit, one of them located in Manastirea (Calarasi) being even 4 times higher. Regarding nitrite, water from one sampling point is over 0.5 mg/L, all the rest being lower and much lower than imposed limit.

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Authors:
Stefanescu Mihai, Badescu Valeriu, Cristea Ionut
Conference: INTERNATIONAL SYMPOSIUM “THE ENVIRONMENT AND THE INDUSTRY”
Date:  26-27 September 2019
Location: Bucharest, Romania
Published: 2019
Keywords:
Ammonia
Chlorination
Sonolysis
Ultrasonic
 
Abstract:
Sonolysis effects are based on ultrasonic cavitation which means generation of very reactive radical especially hydroxyl radical. Its high oxidation potential makes sonolysis one of the best advanced oxidation methods for removal of micropollutants from drinking water sources. Ammonia ions are often present in groundwater sources and must be removed because it favors microorganism development. Chlorination and biological nitrification are the well-known methods for ammonia removal from drinking water. This paper emphasized the alternative of ultrasonic and chlorination for advanced removal of ammonia ions. Laboratory tests have shown 80% ammonia removal efficiency for 9 mg NH4+/L initial concentration for 8.5 reaction pH.
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